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Peter's character is just about the most powerful superhero that has ever been created. But of course the full extent of the powers largely depends on what other people he runs into.

I suppose that's true, to some extent, since his power is really a meta-power to acquire other powers, and there seems to be no boundary to the sort of powers that are out there, somewhere. The related question of whether Peter can adequately control his powers was, I thought, addressed through his interactions with Mr. Invisible, who helped him learn how to control himself. As such, any future explosive events can, perhaps, be interpreted as being something he did deliberately.

(I'm sure that even Sylar needs to practice his powers. I'm modestly curious if/how Sylar figured out how to squelch the super-hearing he picked up several episodes ago, since that particular power doesn't appear to have an on/off switch.)